|
KMID : 1059519940380080552
|
|
Journal of the Korean Chemical Society
1994 Volume.38 No. 8 p.552 ~ p.561
|
|
|
A Study of the Isomerization Reaction Rates of Azobenzene Derivatives
|
|
Yang See-Young
Kim Jong-Gyu
Huh Young-Duk
Choi Young-Sang
|
|
|
Abstract
|
|
|
|
The cis → trans thermal isomerization of azobenzene derivatives has been studied. A sizable solvent effect on the rates for thermal isomerization of push-pull azobenzenes are observed. It is suggested that the isomerization proceeds via a rotational mechanism. For non push-pull azobenzenes, the lack of solvent effects on the rate of isomerization was observed. This suggests that the isomerization proceeds via an inversional mechanism for non push-pull azobenzenes.
|
|
|
KEYWORD
|
|
|
|
|
|
FullTexts / Linksout information
|
|
|
|
|
|
Listed journal information
|
|
|